1,403 research outputs found

    Stratospheric chemical and thermal response to long-term variability in solar UV irradiance

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    Optimal analysis of in situ data in the western Mediterranean using statistics and cross-validation

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    To study the Mediterranean general circulation, there is a constant need for reliable interpretations of available hydrological observations. Optimal data analyses (in the probabilistic point of view of objective analysis) are fulfilled using an original finite-element technique to minimize the variational principle of the spline procedure. Anyway, a prior statistical knowledge of the problem is required to adapt the optimization criterion to the purpose of this study and to the particular features of the system. The main goal of this paper is to show how the cross-validation methodology can be used to deduce statistical estimators of this information only from the dataset. The authors also give theoretical and/or numerical evidence that modified estimators-using generalized cross-validation or sampling algorithms-are interesting in the analysis optimization process. Finally, results obtained by the application of these methods to a Mediterranean historical database and their comparison with those provided by other techniques show the usefulness and the reliability of the method

    Influence of anthropogenic emissions on tropospheric ozone and its precursors over the Indian tropical region during a monsoon

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    An emission inventory of ozone precursors developed for the year 1991 and 2001 is used in a Chemistry-Transport Model (MOZART) to examine the tropospheric changes in ozone and its precursors that have occurred during the 1990s in the geographical region of India in response to enhanced human activities. The maximum variation in ozone concentration near the surface is found to be around 5-10 ppbv. It reaches 5-7% in the lower part of the free troposphere and 3-5% in the upper troposphere. The maximum decadal increase in CO and NOx is about 50-70 ppbv (10-18%) and 0.5-1.5 ppbv (20-50%), respectively in the boundary layer. However, in most of the troposphere, the relative magnitude reduces with height and becomes less then 5% above 10 km. The variation in some of the volatile organic compounds is found to be significant

    Earth's Future: Navigating the science of the Anthropocene

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    Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/102722/1/eft27.pd

    The effect of the solar rotational irradiance variation on the middle and upper atmosphere calculated by a three-dimensional chemistry-climate model

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    This paper analyzes the effects of the solar rotational (27-day) irradiance variations on the chemical composition and temperature of the stratosphere, mesosphere and lower thermosphere as simulated by the three-dimensional chemistry-climate model HAMMONIA. Different methods are used to analyze the model results, including high resolution spectral and cross-spectral techniques. To force the simulations, an idealized irradiance variation with a constant period of 27 days (apparent solar rotation period) and with constant amplitude is used. While the calculated thermal and chemical responses are very distinct and permanent in the upper atmosphere, the responses in the stratosphere and mesosphere vary considerably in time despite the constant forcing. The responses produced by the model exhibit a non-linear behavior: in general, the response sensitivities (not amplitudes) decrease with increasing amplitude of the forcing. In the extratropics the responses are, in general, seasonally dependent with frequently stronger sensitivities in winter than in summer. Amplitude and phase lag of the ozone response in the tropical stratosphere and lower mesosphere are in satisfactory agreement with available observations. The agreement between the calculated and observed temperature response is generally worse than in the case of ozone

    Implicaciones del cambio climático en la calidad del aire

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    Obstacles and benefits of the implementation of a reduced-rank smoother with a high resolution model of the tropical Atlantic Ocean

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    Most of oceanographic operational centers use three-dimensional data assimilation schemes to produce reanalyses. We investigate here the benefits of a smoother, i.e. a four-dimensional formulation of statistical assimilation. A square-root sequential smoother is implemented with a tropical Atlantic Ocean circulation model. A simple twin experiment is performed to investigate its benefits, compared to its corresponding filter. Despite model's non-linearities and the various approximations used for its implementation, the smoother leads to a better estimation of the ocean state, both on statistical (i.e. mean error level) and dynamical points of view, as expected from linear theory. Smoothed states are more in phase with the dynamics of the reference state, an aspect that is nicely illustrated with the chaotic dynamics of the North Brazil Current rings. We also show that the smoother efficiency is strongly related to the filter configuration. One of the main obstacles to implement the smoother is then to accurately estimate the error covariances of the filter. Considering this, benefits of the smoother are also investigated with a configuration close to situations that can be managed by operational center systems, where covariances matrices are fixed (optimal interpolation). We define here a simplified smoother scheme, called half-fixed basis smoother, that could be implemented with current reanalysis schemes. Its main assumption is to neglect the propagation of the error covariances matrix, what leads to strongly reduce the cost of assimilation. Results illustrate the ability of this smoother to provide a solution more consistent with the dynamics, compared to the filter. The smoother is also able to produce analyses independently of the observation frequency, so the smoothed solution appears more continuous in time, especially in case of a low frenquency observation network
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